Tunneling through magnetic molecules with arbitrary angle between easy axis and magnetic field

Inelastic tunneling through magnetically anisotropic molecules is studied theoretically in the presence of a strong magnetic field. Since the molecular orientation is not well controlled in tunneling experiments, we consider arbitrary angles between easy axis and field. This destroys all conservation laws except that of charge, leading to a rich fine structure in the differential conductance. Besides single molecules we also study monolayers of molecules with either aligned or random easy axes. We show that detailed information on the molecular transitions and orientations can be obtained from the differential conductance for varying magnetic field. For random easy axes, averaging over orientations leads to van Hove singularities in the differential conductance. Rate equations in the sequential-tunneling approximation are employed. An efficient approximation for their solution for complex molecules is presented. The results are applied to Mn12-based magnetic molecules.Comment: 10 pages, 10 figures include

Superconductivity in pure and electron doped MgB2: Transport properties and pressure effects

The normal state and superconducting properties of MgB2 and Mg1-xAlxB2 are discussed based on structural, transport, and high pressure experiments. The positive Seebeck coefficient and its linear temperature dependence for Tc<T<160 K provide evidence that the low-temperature transport in MgB2 is due to hole-like metallic carriers. Structural and transport data show the important role of defects as indicated by the correlation of Tc, the residual resistance ratio, and the microstrain extracted from x-ray spectra. The decrease of Tc with hydrostatic pressure is well explained by the strong-coupling BCS theory. The large scatter of the pressure coefficients of Tc for different MgB2 samples, however, cannot be explained within this theory. We speculate that pressure may increase the defect density, particularly in samples with large initial defect concentration.Comment: Presented at NATO Advanced Research Workshop "New Trends in Superconductivity", Yalta (Ukraine) 16-20 September, 200